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Russia earlier invited OSCE officials and Ukrainian border guards to inspect the Russian humanitarian cargoes.
The convoy of 100 trucks currently staying in Russia's Rostov Region is expected to deliver to Ukraine's Donetsk and Luhansk Regions around 1,000 tons of humanitarian cargo, including building materials, food and medicines.
The first three convoys delivered to the Donetsk and Luhansk Regions some 6,000 tons of food supplies, power generators, medicines, warm clothes and bottled water.